Charge transfer in mixed-valence solids. Part VIII. Contribution of valence delocalisation to the ferromagnetism of Prussian Blue
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 15,p. 1483-1486
- https://doi.org/10.1039/dt9760001483
Abstract
The contribution of mixed-valence electron delocalisation to the ferromagnetic exchange between the iron(III) ions in Prussian Blue {FeIII 4[eII(CN)6]3·14H2O} has been estimated theoretically. Agreement between the calculated and observed values of the Curie temperature is quite good.Keywords
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