Abstract
The synergism of trivalent actinides and lanthanides has been reviewed oritically. Different systems Including β-di-ketones and several other chelating agents with various neutral donors have been discussed. The thermodynamic parameters, effect of diluents, auto-synergism and synergism with eutectic mixtures have been discussed In the case of trivalent actinides and lanthanides. Also the mechanism of synergism and the various possible uses of this phenomenon have been referred to with the possible data available.

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