Some co-ordination complexes of dimethyl- and diphenyl-magnesium with ethers and amines

1 January 1966

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 26-27
https://doi.org/10.1039/j19660000026

Abstract

Co-ordination complexes of dimethyl- and diphenyl-magnesium with 1 mol. of tetramethylethylenediamine and 1,2-dimethoxyethane are described, the soluble complexes being monomeric in benzene solution. The bisamine complex of dimethylmagnesium can be sublimed without decomposition, but the others and the tetramethyl-o-phenylenediamine complex of dimethylmagnesium lose ether or amine when heated. Dimethylmagnesium and trimethylethylenediamine form a dimeric complex analogous to those derived from dimethyl-beryllium and -zinc.

Keywords

MAGNESIUM

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