Hydrolysis of cis-dichlorobis(bipyridyl)-cobalt(III) and -chromium(III) ions, and of their phenanthroline analogues with and without a catalyst
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 1,p. 61
- https://doi.org/10.1039/c29700000061
Abstract
Hydrolysis of the dichlorobis(bipyridyl)-cobalt(III) and -chromium(III) ions and their phenanthroline analogues is slow without a catalyst, but is fast in the presence of the corresponding metal(II) complexes: for the metal(III) complexes the hydrolysis is also base-catalysed, even though a conjugate base mechanism is not possible.Keywords
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