Terminal hydrochalcogenido and bridging selenido derivatives of magnesium supported by tris(3-p-tolylpyrazolyl)hydroborate ligation: the syntheses and structures of [Tp p-Tol]MgEH (E = S, Se) and {[Tp p-Tol]Mg}2Se
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1239-1240
- https://doi.org/10.1039/cc9960001239
Abstract
The first structurally characterized monomeric hydrosulfido and hydroselenido complexes of magnesium, [Tpp-Tol]MgEH (E = S, Se), are synthesized by the reaction of [Tpp-Tol]MgMe with H2S and H2Se, respectively; the hydroselenido complex reacts with [Tpp-Tol]MgMe to give the dinuclear bridging selenido complex {[Tpp-Tol]Mg}2Se.Keywords
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