“Click chemistry”en route to pseudo-starch
- 11 May 2005
- journal article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 3 (12) , 2225-2227
- https://doi.org/10.1039/b504293c
Abstract
Rapid assembly of starch fragment analogues was achieved using “click chemistry”. Specifically, two hexadecasaccharide mimics containing two parallel maltoheptaosyl chains linked via [1,2,3]-triazoles to a maltose core were synthesized using Cu(I)-catalyzed [3 + 2] dipolar cycloaddition of azido saccharides and 6,6′- and 4′,6′-dipropargylated p-methoxyphenyl maltoside.Keywords
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