Synthesis and Reactivity of Stretched-Dihydrogen−Ruthenium Complexes. Unexpected Formation of a Vinylidene Ligand
- 6 August 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (16) , 3471-3473
- https://doi.org/10.1021/om960296a
Abstract
No abstract availableKeywords
This publication has 32 references indexed in Scilit:
- First Observation in a Niobium Complex of the Rotation of a Coordinated H-D Molecule Blocked at the NMR Time ScaleJournal of the American Chemical Society, 1995
- Irreversible rearrangement of half-sandwich ruthenium hydrido-alkynyl complexes to their vinylidene isomersJournal of the Chemical Society, Chemical Communications, 1995
- Stretched Molecular Hydrogen Complexes of Osmium(II): A Quantum Chemical Study of the Influence of the Trans Ligand on Geometries, Spin-Spin Coupling Constants, Bonding, and Charge DistributionsJournal of the American Chemical Society, 1994
- New ruthenium vinylidene complexes as intermediates for the access to .sigma.-acetylide and unsymmetrical trans-diynyl, alkynyl metal complexes. Crystal structures of [(Ph2PCH2PPh2)2(Cl)Ru=C=CH2]PF6 and [(Ph2PCH2PPh2)2(Cl)RuC.tplbond.CH] complexesOrganometallics, 1993
- Coordination chemistry of dihydrogenChemical Reviews, 1993
- Barrier to rotation of the dihydrogen ligand in metal complexesThe Journal of Physical Chemistry, 1993
- Dynamics of the molecular hydrogen ligand in metal complexesSpectrochimica Acta Part A: Molecular Spectroscopy, 1992
- Low-temperature neutron diffraction study of bis(tri-p-tolylphosphine)heptahydridorhenium(VII), [ReH7{P(C6H4CH3-4)3}2]: a polyhydride complex with a short H ? H contact that models an intermediate stage in the oxidative addition of dihydrogen at transition metal centresJournal of the Chemical Society, Chemical Communications, 1991
- Preparation and Reactions of a Novel Five-Coordinate Ruthenium Complex [RuH(BINAP)2]PF6 and Formation of the First Chiral Molecular Hydrogen Complex [RuH(η2-H2)(BINAP)2]PF6 (BINAP = (R)-Bis(diphenylphosphino)-1,1′-binaphthyl)Chemistry Letters, 1988
- Preparation of polyhydride complexes of ruthenium by direct hydrogenation of zerovalent olefinic derivatives. Mononuclear complexes of the type RuH6L2 and RuH4L3. Spontaneous hydrogen-deuterium exchange between the phosphine protons and the solvent catalyzed by RuH4L3Organometallics, 1985