Dipole Velocity and Dipole Length Matrix Elements in π Electron Systems and Configuration Interaction
- 1 May 1955
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (5) , 793-795
- https://doi.org/10.1063/1.1742124
Abstract
Equations relating dipole velocity and dipole length matrix elements have been tested for π electron systems treated by a molecular orbital method. Considerable improvement in the validity of the equations is noted when configuration interaction is included in the calculations.Keywords
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