The rotational Raman spectrum of H2 in water
- 15 January 1989
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 90 (2) , 768-772
- https://doi.org/10.1063/1.456101
Abstract
The first four rotational Raman lines of H2 dissolved in water were observed. The lines broaden considerably, but do not shift in position, compared to the corresponding lines of gas phase H2. The breadth of the lines varies with J and with the change from H2O to D2O. The H2 rotational motion is thought to interact with the librational motion of the water molecules.Keywords
This publication has 8 references indexed in Scilit:
- Computer simulation of the dynamics of aqueous solvationThe Journal of Chemical Physics, 1988
- Rules for resolution correction of measured linewidthsSpectrochimica Acta Part A: Molecular Spectroscopy, 1985
- Calculation of self-broadened widths of rotational Raman lines in H2 and N2Canadian Journal of Physics, 1977
- Infrared Absorption of Diatomic Polar Molecules in Liquid SolutionsThe Journal of Chemical Physics, 1971
- Frequency and intensity measurements on the quadrupole spectrum of molecular hydrogenJournal of Molecular Spectroscopy, 1965
- Line-widths of pressure-broadened spectral linesJournal of Quantitative Spectroscopy and Radiative Transfer, 1962
- Some Properties of the Racah and Associated CoefficientsReviews of Modern Physics, 1952
- Pressure Broadening in the Microwave and Infra-Red RegionsPhysical Review B, 1949