Synthesis of the first organopalladium(IV) cations, including the first X-ray study of isostructural organopalladium(IV) and platinum(IV) complexes, [fac-MMe3{tris(pyrazol-1-yl)methane-N,N′,N′}]I
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1093-1095
- https://doi.org/10.1039/c39870001093
Abstract
Stable organopalladium(IV) complexes [fac-PdMe3(L)]I (L = tridentate nitrogen donor ligand) are formed on oxidative addition of iodomethane to PdMe2(L); the tris (Pyrazol-1-yl)methane complex is isostructural with the platinum(IV) analogue.Keywords
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