Grain‐Boundary Chemistry of Barium Titanate and Strontium Titanate: I, High‐Temperature Equilibrium Space Charge

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Abstract
Direct observations using scanning transmission electron microscopy (STEM) of the grain‐boundary chemistry of selectively doped SrTiO3 and BaTiO3 show the predominant solute segregation in both systems to be that of acceptors (negative effective charge). Appreciable donor segregation is not observed even at lattice concentrations as high as 10 mol%. Donor and acceptor codoped materials show segregation of the acceptor only. The results are consistent with a grain‐boundary space‐charge distribution consisting of a positive boundary and negative space charge. All grain boundaries examined also show an excess of Ti relative to the A‐site cations, suggesting that the positive boundary charge is at least partially accommodated by an excess of Ti ions. The sign and magnitude of the electrostatic potential appear to be remarkably insensitive to changes in lattice defect structure with solute doping. Grain‐boundary chemistry appears dominated by space‐charge segregation, in contrast with the predictions of recent atomistic simulations which neglect the space‐charge potential.

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