ADDITION OF FLUOROACETYLENES TO GROUP V HYDRIDES
- 1 December 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (12) , 3392-3399
- https://doi.org/10.1139/v65-471
Abstract
Compounds of the type R2EH react readily with CF3C≡CCF3 to give R2ECH(CF3)=C(CF3)H (E = N,P, As), and with CF3C≡CH to give R2ECH=CHCF3(E = N, As) and R2EC(CF3)=CH2 (E = As). The isomer distribution of the products is obtained from their n.m.r. spectra and the mechanism of the addition reaction is discussed.Keywords
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