Structure of the Pressure-Induced Infrared Spectrum of Hydrogen in the First Overtone Region

Abstract
The pressure-induced infrared spectrum of hydrogen in the first overtone region (1.1–1.25 μ) has been recorded at various temperatures and pressures. The spectrum observed at 24 K with a path length of 13.6 m and a gas density of 31 amagat is analyzed on the basis of the Van Kranendonk theory of quadrupole-induced absorption. The relative intensities of the 15 single and double transitions composing the band and the integrated intensity of the band are in satisfactory agreement with the theory.

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