Rhenium complexes containing an η2-thiocarbamoyl group: synthesis, electrochemistry, and crystal structure of [Re(S2CNEt2)2(SCNEt2)(PPh3)]ClO4
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1130-1131
- https://doi.org/10.1039/c39880001130
Abstract
A new redox couple of rhenium complexes, [ReIII(S2CNEt2)2(SCNEt2)(PPh3)] and [ReIV(S2CNEt2)2(SCNEt2)(PPh3)]ClO4, has been isolated and electrochemically characterized; the η2-co-ordination of the N,N-diethylthiocarbamoyl group in the latter has been confirmed by X-ray analysis.Keywords
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