Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 715-716
- https://doi.org/10.1039/a700663b
Abstract
Reactions of aromatic imines with the putative butatrienylidene–ruthenium cation [Ru(CCCCH 2 )(PPh 3 ) 2 - (η-C 5 H 5 )] + gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(CCC 9 H 4 MeN)(PPh 3 ) 2 (η-C 5 H 5 )] and [Ru{CCC(CHCHPh)N(C 6 H 4 N O 2 -3)}(PPh 3 ) 2 (η-C 5 H 5 )] are reported.Keywords
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