Generation of ethyl thioxoacetate, a dienophilic thioaldehyde
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 423-425
- https://doi.org/10.1039/c39830000423
Abstract
Ethoxycarbonylmethanesulphenyl chloride reacts with triethylamine to give the transient thioaldehyde, ethyl thioxoacetate, which has been trapped, in situ, by cycloaddition to various conjugated dienes.Keywords
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