Carbonyl halides of the Group VI transition metals. III. Tungsten halocarbonyls and some of their derivatives

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Abstract
The unstable compounds dichlorotetracarbonyltungsten(II) and dibromo- tetracarbonyltungsten(II) have been prepared but not isolated in a pure state. The π-bonding ligands triphenylphosphine, triphenylarsine, and triphenylstibine have been used to prepare a series of moderately stable derivatives.

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