Diastereoselective anionic and radical conjugate addition on a chiral enone: a route to multichiral arrays
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 399-401
- https://doi.org/10.1039/c39940000399
Abstract
1,4 Addition of several alkyl groups using cuprates and radicals on a conformationally biased chiral enone 3 derived from carbohydrate is described, showing essentially identical diastereoselection in anionic and radical processes and a dramatic influence of the alkyl group size on the sense of 1,2-asymmetric induction.Keywords
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