Notes. Tin-119 and nitrogen-14 nuclear magnetic resonance and tin-119 variable-temperature Mössbauer spectroscopic study of tricyclohexyltin isothiocyanate including the first observation of resolved117,119Sn–14N coupling in an organotin compound
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 875-877
- https://doi.org/10.1039/dt9860000875
Abstract
Resolved 117.119Sn–14N coupling has been observed for the first time in an organotin compound in tricyclohexyltin Isothiocyanate, with 1J(119Sn–14N)= 136 Hz. Variable-temperature Mössbauer spectroscopic data for SnR3(NCS)(R = C6H5 or C6H11) are interpreted in terms of the tertiary structure of the co-ordination polymer changing from an ‘S’ shape (R = C6H5, a=– dln f/dT= 1.84 × 10–2 K–1) towards a more linear arrangement (R = C6H11, a= 1.34 × 10–2 K–1).This publication has 2 references indexed in Scilit:
- Organotin biocides. Part 2. Variable-temperature119Sn Mössbauer study of phenyl- and cyclohexyl-tin compoundsJ. Chem. Soc., Dalton Trans., 1985
- Structure-activity relationships in triorganotin biocides: The influence of the anionic radicalPesticide Science, 1984