Reaction between Various Copper(II) Complexes and Ascorbic Acid or 3,5-Di-t-butylcatechol
- 1 October 1980
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (10) , 2847-2850
- https://doi.org/10.1246/bcsj.53.2847
Abstract
The electron transfer reactions between various copper(II) complexes and two-electron donors, such as ascorbic acid and 3,5-di-t-butylcatechol, were investigated. Mononuclear copper(II) complexes with a distorted tetrahedral and a trigonal bipyramidal structure, and some binuclear complexes were readily reduced to copper(I) complexes by the two-electron donors, but not mononuclear planar copper(II) complexes. The catalytic activities of these copper(II) complexes for the oxidation of 3,5-di-t-butylcatechol by O2 were studied in relation to the above reactions.Keywords
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