Disilanyl Group as a Synthetic Equivalent of the Hydroxyl Group
- 1 September 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (09) , 941-942
- https://doi.org/10.1055/s-1995-5150
Abstract
Disilanyl groups are readily converted to hydroxy group by quite simple one-pot operation including treatment with tetrabutylammonium fluoride (TBAF) followed by oxidation. Synthetic utility of the new, stable hydroxy equivalent was demonstrated by synthesis of 5-membered cyclic ketones via annulation of allenyldisilanes with α,β-unsaturated ketones.Keywords
This publication has 0 references indexed in Scilit: