HgF2-assisted additions to SN and CN triple bonds
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 839-840
- https://doi.org/10.1039/c39820000839
Abstract
Formal additions of CIF to the SN triple bond in NSF3 and to the CN triple bond in CF3CN and (CN)2 are achieved by the system Cl2–HgF2; N-bromo-amines and -imines are isolated from RfCN–Br2–HgF2·NSF3 and CF3SCl–HgF2 gives SF5N(SCF3)2 in high yield.Keywords
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