Chemie der Isoblausäure, II Reaktionen von [M(CO)5CNH] (M = Cr, Mo, W) mit Aziridinen: Zyklische Diaminocarbenkomplexe / Chemistry of Hydrogen Isocyanide, II Reactions of [M(CO)5CNH] (M = Cr, Mo, W) with Aziridines: Cyclic Diaminocarbene Complexes
Open Access
- 1 August 1986
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 41 (8) , 1023-1027
- https://doi.org/10.1515/znb-1986-0816
Abstract
The hydrogen isocyanide complexes [M (CO)5CNH] (M = Cr, Mo, W) have been treated with the aziridines R [xxx] H2 (R = H, R’ = H, Me, Et; R = Me, R’ = H) to give imidazolidin-2-ylidene complexes. The same type of ligand forms on addition of aziridine to the electrophilic isocyanide group in [FpCNPh]+ in the presence of Br−, IR, 1H NMR, 13C NMR and mass spectra of the new compounds are reported.Keywords
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