Regioselective functionalisation of triamantane
- 1 January 1978
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 306-308
- https://doi.org/10.1039/c39780000306
Abstract
The C18H24 diamondoid hydrocarbon triamantane reacts with bromine largely at the 2-position and with lead tetrabenzoate largely at the 3-position; 2-bromotriamantane can be isomerised to 9-bromotriamantane and the 9-methyl derivative can be obtained directly from a C19H26 precursor by aluminium chloride-catalysed rearrangement.Keywords
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