Claisen rearrangements in the biosynthesis of 1,1- and 1,2-dimethylallyl derivatives. The biosynthesis of the quinoline alkaloid, ravenoline
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 21,p. 1269b-1270
- https://doi.org/10.1039/c2969001269b
Abstract
The origin of 1,1- and 1,2-dimethylallyl residues in aryl and heterocyclic compounds is discussed, and the biosynthesis of the 1,2-dimethylallyl derivative, ravenoline, is shown to occur by rearrangement of a 3,3-dimethylallyl ether.Keywords
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