Acceleration of the 4-exo radical cyclization to a synthetically useful rate. Cyclization of the 2,2-dimethyl-5-cyano-4-pentenyl radical
- 1 January 1990
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 31 (21) , 2975-2978
- https://doi.org/10.1016/s0040-4039(00)89002-4
Abstract
No abstract availableThis publication has 24 references indexed in Scilit:
- Carbocyclic ring expansion reactiuon VIA radical chain processesTetrahedron, 1989
- Radical macrocyclisations in synthesis. A new approach to mukulol and marine cembranolide lactonesTetrahedron Letters, 1989
- A convenient method for kinetic studies of fast radical rearrangements. Rate constants and Arrhenius function for the cyclopropylcarbinyl radical ring openingJournal of the American Chemical Society, 1989
- Free-radical macrocyclization-transannular cyclizationJournal of the American Chemical Society, 1988
- A new tributyltin hydride-based rearrangement of bromomethyl .beta.-keto esters. A synthetically useful ring expansion to .gamma.-keto estersJournal of the American Chemical Society, 1987
- Cyano or acyl group migration by consecutive homolytic addition and β-fissionJournal of the Chemical Society, Chemical Communications, 1987
- Absolute rate constants for reaction of phenyl, 2,2-dimethylvinyl, cyclopropyl, and neopentyl radicals with tri-n-butylstannane. Comparison of the radical trapping abilities of tri-n-butylstannane and -germaneJournal of the American Chemical Society, 1985
- Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydrideJournal of the American Chemical Society, 1981
- Addition of carbon tetrachloride to 3,3,4,4-tetrafluorohexa-1,5-dieneJournal of the Chemical Society, Perkin Transactions 1, 1973
- Reactions of 3,3,4,4-tetrafluorohexa-1,5-diene. Part II. Cyclisation to a four-membered ring in the thermal addition of pentafluoroiodoethaneJournal of the Chemical Society C: Organic, 1971