Studies in decarboxylation. Part 16. Steric inhibition of resonance in a 1,5-sigmatropic reaction
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 9,p. 1311-1312
- https://doi.org/10.1039/p29830001311
Abstract
The rates of gas-phase decarboxylation of some 3-phenyl-substituted but-3-enoic acids are best rationalized in terms of steric inhibition of resonance in the more sterically crowded members.Keywords
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