Stability and Bonding Situation of Electron-Deficient Transition-Metal Complexes. Theoretical Study of the CO-Labilizing Effect of Ligands L in [W(CO)5L] (L = C2H2, NCH, N2, C2H4, OH2, SH2, NH3, F-, Cl-, OH-, SH-) and [W(CO)4L]2- (L2- = O2C2H22-, S2C2H22-) and the Structure of the 16-Valence-Electron Complexes [W(CO)4L] and [W(CO)3L]2- †
- 17 May 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 20 (12) , 2510-2524
- https://doi.org/10.1021/om0101893
Abstract
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This publication has 48 references indexed in Scilit:
- The Nature of the Transition Metal−Carbonyl Bond and the Question about the Valence Orbitals of Transition Metals. A Bond-Energy Decomposition Analysis of TM(CO)6q (TMq = Hf2-, Ta-, W, Re+, Os2+, Ir3+)Journal of the American Chemical Society, 2000
- A Valence Bond Perspective on the Molecular Shapes of Simple Metal Alkyls and HydridesJournal of the American Chemical Society, 1998
- Molecular structure and binding energies of monosubstituted hexacarbonyls of chromium, molybdenum, and tungsten: Relativistic density functional studyJournal of Computational Chemistry, 1997
- Electronic Structure of Stable Carbenes, Silylenes, and GermylenesJournal of the American Chemical Society, 1996
- On the Question of Stability, Conjugation, and “Aromaticity” in Imidazol-2-ylidenes and Their Silicon AnalogsJournal of the American Chemical Society, 1996
- A stable diaminocarbeneJournal of the American Chemical Society, 1995
- Theoretical study of the structures of electron-deficient d6 ML5 complexes. Importance of a .pi.-donating ligandOrganometallics, 1992
- Hypercoordinate molecules of second-row elements: d functions or d orbitals?Journal of the American Chemical Society, 1990
- Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitalsThe Journal of Chemical Physics, 1985
- Electronic structure of chromium hexacarbonyl at 78 K. I. Neutron diffraction studyActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1975