Struktur eines Spirobi(cyclophosphazens) [1] / Structure of a Spirobi(cyclophosphazene) [1]
Open Access
- 1 July 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (7) , 911-914
- https://doi.org/10.1515/znb-1979-0705
Abstract
Proton addition to the spirobi(cyclotriphosphazene) anion 1 gives the neutral species 2. An X-ray structure determination shows the proton to be located at a nitrogen atom next t o the spirocenter. The structural consequences of this protonation can be demonstrated by comparisons of intramolecular bond distances and angles and can be understood in terms of structure-determining repulsive N/N interactions in the central PN4 unitKeywords
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