Energy profile of rapid, reversible oxidative addition reaction
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2115-2116
- https://doi.org/10.1039/c39950002115
Abstract
The trimethyltin undergo a very fast, reversible oxidative addition reaction with [PtMe2(Bu2bipy)], Bu2bipy = 4,4′-di-tert-butyl-2,2′-bipyridine, to give [PtXMe2(SnMe3)(Bu2bipy)] for which a complete energy profile can be obtained by using variable-temperature NMR methods; the reaction with X = I is the fastest known oxidative addition and activation energies when X = Cl suggest detailed structure for the transition state.Keywords
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