Boundary Film Formation by Viscosity Index Improvers

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Abstract
Ultrathin film interferometry has been used to measure the film-forming properties of a range of viscosity index improver (VII) solutions in rolling, concentrated contacts. It has been shown that some VIIs form boundary lubricating films of thickness 10 to 30 nm in contacts. These films result from the presence of highly concentrated and thus very viscous layers of polymer solution formed on the two rubbing solid surfaces by polymer adsorption. These boundary films are formed only by some types of VII and can persist up to temperatures in excess of 120°C. The possible implications of this type of boundary lubrication are discussed.