Coordination of Cu(II) in Cu(NO3)2 aqueous solutions
- 15 May 1984
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 80 (10) , 5308-5311
- https://doi.org/10.1063/1.446559
Abstract
Two concentrated copper (II) nitrate solutions have been examined by x‐ray diffraction. The inspection of the radial distribution curves and the direct fitting of the structure functions suggested that a distorted arrangement of six oxygen atoms exists around the Cu2+ ion, probably in a tetragonally distorted, elongated octahedron. The best agreement with experimental data was achieved through a model in which extensive inner‐sphere complex formation between Cu2+ and NO−3 ions takes place.Keywords
This publication has 15 references indexed in Scilit:
- Coordination of copper(II) in aqueous copper sulfate solutionInorganic Chemistry, 1983
- The sulphate ion in aqueous solution: an X-ray diffraction study of a ZnSO4solutionJournal of Applied Crystallography, 1982
- Coordination of copper(II). Evidence of the Jahn-Teller effect in aqueous perchlorate solutionsInorganic Chemistry, 1982
- The coordination (hydration) of rare earth ions in aqueous chloride solutions from x ray diffraction. I.TbCl3,DyCl3, ErCl3,TmCl3,and LuCl3The Journal of Chemical Physics, 1979
- Diffraction of X-rays and hydration phenomena in aqueous solutions of Mg(NO3)2Chemical Physics Letters, 1979
- The crystal and molecular structures of hexaaquacopper(II) benzenesulphonate, toluene-4-sulphonate and D-camphor-10-sulphonateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1978
- On NO−3–H2O interactions in aqueous solutionsThe Journal of Chemical Physics, 1978
- X-ray diffraction study of Cr(NO3)3 aqueous solutionsChemical Physics, 1977
- X-ray diffraction study of the average solute species in CaCl2 aqueous solutionsThe Journal of Chemical Physics, 1976
- Laser Raman study of aqueous copper nitrate solutionsInorganic Chemistry, 1972