Zur Einwirkung von OH-Radikalen auf Phosphonsäureester vom Trichlorphontyp
Open Access
- 1 February 1970
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 25 (2) , 152-155
- https://doi.org/10.1515/znb-1970-0206
Abstract
The formation of two different types of radicals in phosphonic acid esters (0-dimethyl-[1-hydroxy-2,2,2-trichloroethyl] -phosphonate, trichlorphon; O,O-dimethyl- [1-hydroxy-l-methylethyl] -phosphonate) folowing reaction with OH radicals is shown by ESR Hfs. Coupling constants for H, P and Cl and g-values are given and discussed. The results in liquid phase (oxidation by OH) are compared with results on radiation-induced radicals in solid trichlorphon.Keywords
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