Etude de la cinétique d'une réaction de cyclisation simple
- 1 January 1954
- journal article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 37 (4) , 1351-1360
- https://doi.org/10.1002/hlca.19540370444
Abstract
TheArrheniusparameters for the unimolecular lactonisation of the K‐salts of the ω‐brom‐undecanoic and ω‐brom‐pentadecanoic acids have been determined. It has been shown that the reaction rate depends on the ionisation of the bromine, not on the cyclisation process. The observations have been discussed and, in particular, an explanation in kinetic terms is provided for the minimum yield of cyclic products near C11.Keywords
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