The thermal conductivity of polyatomic molecules
- 1 October 1988
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 89 (7) , 4333-4338
- https://doi.org/10.1063/1.454817
Abstract
We show that by means of a linear transformation of the trial functions in the second approximation to the distribution function, a simple expression for the thermal conductivity of polyatomic molecules can be obtained. This is made possible using our results of state-selective measurements of the nonequilibrium distribution in a heat conducting gas. Also a direct relationship between the pure gas transport coefficients can be deduced, which gives an accurate description of both monatomic and polyatomic gases. This is illustrated by a comparison between calculated and experimental data of the thermal conductivity.Keywords
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