Abstract
The oxyfluorides A2NbOF5 and A,MoO2F4 (A = Rb, Cs, NH4) were prepared and investigated by x-rays. Rb2NbOF5 and Cs2NbOF5 crystallize hexagonally (K2GeF6-type); the compounds A2MoO2F4 and (NH4) 2NbOF5 show orthorhombic symmetry.

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