Total synthesis of urdamycinone B via C-glycosidation of an unprotected sugar and Diels–Alder reaction of C-glycosyl juglone
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 225-226
- https://doi.org/10.1039/cc9960000225
Abstract
The total synthesis of C-glycosyl angucycline, urdamycinone B 1, was achieved via C-glycosidation of naphthol 6 and the unprotected D-olivose 7, and Diels–Alder reaction of the unprotected C-glycosyl juglone 9 and the diene 17 as the key steps.Keywords
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