The solution of the reference hypernetted-chain approximation for water-like models

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Abstract
In this paper we examine the dielectric and structural properties of hard polarizable multipolar models for liquid water. The theoretical results were obtained by solving the self-consistent mean field (SCMF) approximation together with the reference hypernetted-chain (RHNC) theory. The dielectric constants are in good agreement with experiment over a large range of temperatures and pressures. The rather poor agreement between the radial distribution functions determined for our water-like fluids at 25°C and those measured for liquid water is discussed.