Self-assembly and X-ray structure of a ten-component, three-dimensional metallosupramolecular cage
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 6,p. 541-542
- https://doi.org/10.1039/a608081b
Abstract
Reaction of 1,3,5-tris(pyrazol-1-ylmethyl)-2,4,6-triethyl-benzene 7 with palladium chloride results in the self-assembly of a three-dimensional cage; an X-ray crystal structure determination shows that the cage is comprised of an octahedral arrangement of six palladium atoms bridged by a tetrahedral network of four molecules of the ligand and contains a (disordered) guest molecule of dimethyl sulfoxide.Keywords
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