Alternating copolymer of butadiene and propylene. III
- 1 March 1972
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A-1: Polymer Chemistry
- Vol. 10 (3) , 681-688
- https://doi.org/10.1002/pol.1972.150100305
Abstract
Alternating copolymerizations of butadiene with propylene and other olefins were investigated by using VO(acac)2–Et3Al–Et2AlCl system as catalyst. Butadiene–propylene copolymer with high degree of alternation was prepared with a monomer feed ratio (propylene/butadiene) of 4. Alternating copolymers of butadiene and other terminal olefins such as butene‐1, pentene‐1, dodecene‐1, and octadiene‐1,7 were also obtained. However, the butadiene–butene‐2 copolymerization did not yield an alternating copolymer but a trans‐1,4‐polybutadiene.Keywords
This publication has 2 references indexed in Scilit:
- An alternating copolymer of butadiene and propyleneJournal of Polymer Science Part B: Polymer Letters, 1969
- Alternating‐type copolymerizations of butadiene and propylene IIJournal of Polymer Science Part B: Polymer Letters, 1969