Reactions of Unsaturated Compounds with Silicon Difluoride. Part I. Acetylene
- 15 February 1972
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 50 (4) , 459-464
- https://doi.org/10.1139/v72-071
Abstract
The reaction of acetylene with silicon difluoride at low temperatures has been studied. Three products have been identified as volatile species after the reaction: tetrafluorodisilacyclobutene, 3,4-tetrafluorodisilahex-1-yne-5-ene, and 5,6,7-hexafluorotrisilanorborn-2-ene. Spectroscopic data for the compounds are presented, together with a possible mechanism to account for the formation of the observed products.Keywords
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