ESR of V4+ions in α-berlinite AlPO4
- 28 February 1982
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 15 (6) , 1297-1300
- https://doi.org/10.1088/0022-3719/15/6/022
Abstract
The X-band ESR spectrum of vanadium-doped alpha -berlinite AlPO4 has been observed at room temperature. The spectrum, attributed to V4+ in a distorted tetrahedral site, can be described by a spin Hamiltonian of axial symmetry. The Hamiltonian parameters are: g/sub ///=1.9278, gperpendicular to =1.9759, mod A/sub /// mod =175*10-4 cm-1, mod Aperpendicular to mod =66*10-4 cm-1. The wavefunction of the ground state is of the dx-y type (where x-y=x2-y2).Keywords
This publication has 8 references indexed in Scilit:
- ESR of V4+ions alpha cristobalite AlPO4Journal of Physics C: Solid State Physics, 1980
- Verfeinerung der Struktur der Tiefquarz-Modifikation von AlPO4Zeitschrift für Kristallographie, 1966
- Paramagnetic Resonance of Vanadium in Amorphous and Polycrystalline GePhysical Review B, 1964
- Refinement of the atomic parameters of α-quartzActa Crystallographica, 1963
- Electron resonance studies of transition metal oxyions, I. Experimental results for the manganate, hypomanganate and ferrate ionsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1960
- Electron Spin Resonance of Mn-activated PhosphorsJournal of the Physics Society Japan, 1959
- Paramagnetic resonance of divalent manganese incorporated in various latticesDiscussions of the Faraday Society, 1955
- CRYSTALLOGRAPHIC INVERSIONS OF THE ALUMINUM ORTHOPHOSPHATE POLYMORPHS AND THEIR RELATION TO THOSE OF SILICA*Journal of the American Ceramic Society, 1949