Grain growth control in ZnO varistors using seed grains

Abstract
A method for making low‐voltage ZnO varistors having extraordinarily large grain size without necessity of sintering at much higher temperatures or for much longer times is reported. The device is made by sintering a mixture of ZnO fine powder, additives, and ZnO seed grains having grain sizes of 63–105 μm obtained by washing a ZnO sintered body containing BaO in boiling water. The device has a grain size around 500 μm and low threshold voltage of 6 V/mm. Such anomalous grain growth is caused by the difference between the radii of curvature of ZnO fine powder and ZnO seed grains.

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