Stepwise bond dissociation energies for the removal of fluorine from thionyl fluoride and sulphuryl fluoride
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1228-1229
- https://doi.org/10.1039/c39800001228
Abstract
Detailed energy balance studies of the single-collision chemiluminescent reactions of metastable strontium atoms with thionyl fluoride and sulphuryl fluoride yield the bond dissociation energies: D0 ⊖(FSO–F) 362 ± 19, D0 ⊖(SO–F) 337 ± 106, D0 ⊖(FSO2–F) 379 ± 18, and D0 ⊖(SO2–F) 229 ± 20 kJ mol–1.Keywords
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