Application of a High-Speed Electronic Computer in Diffusion Kinetics. II. Depletion Effect in the Spherical One-Radical One-Solute Model
- 1 April 1960
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 32 (4) , 1183-1184
- https://doi.org/10.1063/1.1730871
Abstract
The earlier computations [D. A. Flanders and H. Fricke, J. Chem. Phys. 28, 1126 (1958)] on the Spherical One‐Radical One‐Solute model were extended by taking account of the transient dilution of the solute which occurs during the reaction. Although the drop in concentration of the solute near the center of the reaction zone may be considerable, its effect on the fraction of radicals combining with the solute is only of the order of one percent under the most unfavorable conditions likely to be encountered when the model is applied to γ‐irradiated aqueous solutions.Keywords
This publication has 1 reference indexed in Scilit:
- Application of a High-Speed Electronic Computer in Diffusion KineticsThe Journal of Chemical Physics, 1958