Reduction of intermolecular association in the sterically encumbered (dichloroiodo)arene ArICl2[Ar = 2,6-bis(3,5-dichloro-2,4,6-trimethylphenyl)benzene]
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1115-1116
- https://doi.org/10.1039/c39950001115
Abstract
The synthesis of the sterically encumbered (dichloroiodo)arene ArICl2[Ar = 2,6-bis(3,5-dichloro-2,4,6-trimethyl-phenyl)benzene] is achieved via a novel hexachlorination reaction and an X-ray structural determination reveals a reduced intermolecular association for the hypervalent iodine species as compared to the only other crystallographically characterized (dichloroiodo)arene PhICl2(the structure of which is re-examined in light of the present data).Keywords
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