Two-electron, three-centre carbon–hydrogen–cobalt bonds in the compounds [Co(η-C5Me4R)(η-C2H4)(η-C2H4-µ-H)] BF4, R = Me and Et
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 691-693
- https://doi.org/10.1039/c39830000691
Abstract
Protonation of Co(η-C5H4R)(η-C2H4)2, R = Me or Et with tetrafluoroboric acid gives the compounds [Co(η-C5Me4R)(η-C2H4)Et]Bf4, R = Me (1) or Et (2), in which a β-hydrogen of the Co–ethyl group forms a C–HCo bridge via a two-electron, three-centre bond.Keywords
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