Excellent Z-Selective Olefin Formation Using Pentacoordinate Spirophosphoranes and Aldehydes. Wittig Type Reaction via Hexacoordinate Intermediates

This publication has 11 references indexed in Scilit:

• Reactivity of Carbon Anions α to Pentacoordinated Phosphorus: SpirooxyphosphoranylC-Anions as Valuable Intermediates in Olefination Chemistry
  Journal of the American Chemical Society, 1996
• Characterization of Enantiomeric Pairs of Optically Active 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus
  Bulletin of the Chemical Society of Japan, 1995
• Practical synthesis of Z-unsaturated esters by using a new Horner-Emmons reagent, ethyl diphenylphosphonoacetate
  Tetrahedron Letters, 1995
• Non-dissociative permutation of a stable hydrophosphorane and retention of stereochemistry of the electrophilic reaction of its conjugate phosphoranide base
  Tetrahedron Letters, 1995
• Synthesis, Structure, and Thermolysis of a 3‐Methoxycarbonyl‐1, 2 λ⁵‐oxaphosphetane
  Angewandte Chemie International Edition in English, 1993
• New triply hydrogen bonded complexes with highly variable stabilities
  Journal of the American Chemical Society, 1992
• Palladium(0)-catalyzed reaction of (Z)-2-butene-1,4-diyl bis(methyl carbonate) and (Z)-2-butene-1,4-diyl diacetate with bifunctional nitrogen nucleophiles
  The Journal of Organic Chemistry, 1990
• Kinetic facial selectivity in nucleophilic displacements at tetracoordinate phosphorus: kinetics and stereochemistry in the reaction of sodium ethoxide with O,S-dimethyl phenylphosphonothioate
  Journal of the American Chemical Society, 1989
• Direct synthesis of Z-unsaturated esters. A useful modification of the horner-emmons olefination.
  Tetrahedron Letters, 1983
• Directed dilithiation of hexafluorocumyl alcohol - formation of a reagent for the facile introduction of a stabilizing bidentate ligand in compounds of hypervalent sulfur (10-S-4), phosphorus (10-P-5), silicon (10-Si-5), and iodine (10-I-3)
  The Journal of Organic Chemistry, 1981