The crystal structure of C12H16Ru4(CO)10: an open Ru4 cluster containing a novel three-carbon bridging group
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1159
- https://doi.org/10.1039/c29700001159
Abstract
The electron-deficient complex C12H16Ru4(CO)10 is shown to contain an open Ru4 cluster; the monocyclic C12 ring is attached to the cluster by a conventional π-allyl bond to one ruthenium atom, and by a novel bridging C3 unit, which is π-bonded to the two apical metal atoms, and σ-bonded to each of the “hinge” metal atoms.Keywords
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