Vibration-to-rotation energy transfer in hydrogen fluoride: Effects of the dipole-dipole and hydrogen-bond interactions
- 15 July 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (2) , 879-884
- https://doi.org/10.1063/1.1680108
Abstract
The importance of the dipole‐dipole and hydrogen‐bond interactions in the vibration‐to‐rotation energy transfer in hydrogen fluoride molecules is investigated in the temperature range of 300 to 4000°K. The collision trajectory and collision time are evaluated for the over‐all potential energy constructed from the sum of the exponential (Morse‐type) and dipole‐dipole interaction functions. Good agreement between the present calculations and experiment is found over the entire temperature range.Keywords
This publication has 18 references indexed in Scilit:
- HF Vibrational Relaxation Measurements Using the Combined Shock Tube-Laser-Induced Fluorescence TechniqueThe Journal of Chemical Physics, 1972
- Vibrational Energy Transfer and De-excitation in the HF, DF, HF–CO2, and DF–CO2 SystemsThe Journal of Chemical Physics, 1972
- Effects of Deviations from the Bethe Model on LEED Intensities for an Exactly Soluble One‐Dimensional ModelThe Journal of Chemical Physics, 1972
- Radiofrequency and Microwave Spectrum of the Hydrogen Fluoride Dimer; a Nonrigid MoleculeThe Journal of Chemical Physics, 1972
- Shock-Tube Studies of HF Vibrational RelaxationThe Journal of Chemical Physics, 1971
- The vibrational excitation of hydrogen fluoride behind incident shock wavesInternational Journal of Chemical Kinetics, 1971
- De-Excitation of molecular vibration on collision: vibration-to-rotation energy transfer in hydrogen halidesThe Journal of Physical Chemistry, 1971
- Excitation of molecular vibration on collision. Oriented nonlinear encountersThe Journal of Physical Chemistry, 1969
- Chemical Laser by Fluid MixingThe Journal of Chemical Physics, 1969
- The crystal structure of hydrogen fluorideActa Crystallographica, 1954